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Why is the  \mathrm{\sigma 2 p_z} orbital the LUMO of  \mathrm{B_2} molecule? 

Option: 1

Because it is the highest energy orbital.
 


Option: 2

Because it is the most unstable orbital.
 


Option: 3

Because it is the orbital that is most easily excited.
 


Option: 4

Because it is the orbital that is most likely to interact with other molecules.


Answers (1)

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The \sigma 2 p_z orbital is the LUMO of \mathrm{B_2} molecule because it is the orbital that is most easily excited. This is because the \mathrm{\sigma 2 p_z} orbital is relatively high in energy, and it is also the orbital that is most exposed to the environment. This means that it is more likely to interact with other molecules and to be excited to a higher energy level.

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Divya Prakash Singh

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