Why is phosphoric acid preferred over sulphuric acid when reacting with hydrated barium peroxide ?
Phosphoric acid forms a protective coating with barium peroxide.
Sulphuric acid decomposes hydrogen peroxide, while phosphoric acid acts as a preservative.
Sulphuric acid prevents the formation of soluble impurities.
Phosphoric acid enhances the reactivity of barium peroxide.
When using sulphuric acid, soluble impurities like barium persulphate can form, and these impurities tend to decompose hydrogen peroxide. In contrast, phosphoric acid acts as a preservative or negative catalyst for hydrogen peroxide, preventing its decomposition.