Thermodynamics mainly deals with
(i) interrelation of various forms of energy and their transformation front one form to another.
(ii) energy changes in the processes which depend only on initial and final states of the microscopic system containing a few molecules.
(iii) how and at what rate these energy transformations are carried out.
(iv) the system in equilibrium state or moving from one equilibrium state to another equilibrium state.
The answer is option (i) and (iv)
Explanation: The prerequisite conditions required for the thermodynamics laws to be applicable is for the system to be in equilibrium. Also, they are relevant to the macroscopic systems and not to the microscopic systems which have very few numbers of molecules.