Get Answers to all your Questions

header-bg qa

Diatomic molecules like hydrogen have energies due to both translational as well as rotational motion. From the equation in kinetic theory PV = \frac{2}{3}E, E is
(a) the total energy per unit volume
(b) only the translational part of energy because rotational energy is very small compared to the translational energy
(c) only the translational part of the energy because during collisions with the wall pressure relates to change in linear momentum
(d) the translational part of the energy because rotational energies of molecules can be of either sign and its average over all the molecules is zero

Answers (1)

The correct answer is the option (c)

As per the kinetic theory of gases, the perpendicular forces exerted by the molecules on the walls while in motion are only responsible for the pressure exerted due to the gas molecules. So, for molecules striking at angles other than 90 degrees, no pressure will be exerted. Hence, in this case, only translational motion change leads to pressure on the wall. So, PV = \frac{2}{3}E, which represents the translational motion part and hence c is the correct option.

Posted by

infoexpert24

View full answer