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Grapes hanging on the plant do not ferment but after being plucked from the plant can be fermented. Under what conditions do these grapes ferment? Is it a chemical or a physical change?

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Grapes on the plant do not ferment because of defense mechanism of plants. When grapes are plucked from plant, grapes reacts with yeast to carry out fermentation. Here sugar changes to alcohol and it is a chemical change. 

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