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  • Which of the following complexes show linkage isomerism? (i) [Co(NH_{3})_{5}(NO_{2})]^{2+} (ii) [Co(H_{2}O)_{5}CO]^{3+} (iii) [Cr(NH_{3})_{5}SCN]^{2+} (iv) [Fe(en)_{2}Cl_{2}]^{+}

Which of the following complexes show linkage isomerism?

(i) [Co(NH_{3})_{5}(NO_{2})]^{2+}

(ii) [Co(H_{2}O)_{5}CO]^{3+}

(iii) [Cr(NH_{3})_{5}SCN]^{2+}

(iv) [Fe(en)_{2}Cl_{2}]^{+}

Answers (1)

Option (i) and (iii) are the correct answers.

Explanation: NO_{2}  and SCN show linkage isomerism because they are ambidentate ligands.

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