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Give the reaction involved during extraction of zinc from its ore by
(a) roasting of zinc ore
(b) calcination of zinc ore

Answers (1)

Roasting: method by which a sulphide ore is converted into oxide
Calcination: method by which a carbonate ore is converted into oxide
(a) Roasting of zinc ore: Sulphide ore of zinc is ZnS (zinc blende)
2ZnS\left ( s \right )+3O_{2}\rightarrow 2ZnO\left ( s \right )+2SO_{2}
ZnO is then reduced to zinc by heating with coke (carbon)
ZnO\left ( s \right )+C\left ( s \right )\rightarrow Zn\left ( s \right )+CO\left ( g \right )
(b) Calcination of zinc ore: Carbonate ore of Zinc is calamine ZnCO3
ZnCO_{3}\left ( s \right )\rightarrow ZnO\left ( s \right )+CO_{2}\left ( g \right )
ZnO is then reduced to zinc by heating with coke (carbon)
ZnO\left ( s \right )+C\left ( s \right )\rightarrow Zn\left ( s \right )+CO\left ( g \right )

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